(Received: December 28, 2006; Accepted for publication: May 22, 2007; Published on Web: July 23, 2007)
Numerical methods for the eigenvalue problem of second-order ordinary differential equations are presented. One is the discretized matrix eigenvalue method and another is the shooting method. In the former method, derivative with respect to spatial coordinate is discretized, thus the ordinary differential equation is transformed into matrix eigenvalue problems, then the matrix eigenvalue problems are solved numerically. The latter method has three steps. Firstly, initial values for the eigenvalue and eigenfunction at both ends are obtained by using the discretized matrix eigenvalue method. Secondly, the initial-value problem is solved using new, highly accurate formulas of the linear multistep method. Thirdly, the eigenvalue is properly corrected at the matching point. The efficiency of the proposed methods is demonstrated by their applications to bound states for the one-dimensional harmonic oscillator and anharmonic oscillators, the Morse potential and the modified Poschl-Teller potential in quantum mechanics.
Keywords: Eigenvalue problem, Ordinary differential equation, Discretized matrix eigenvalue method, Shooting method, Harmonic oscillator, Anharmonic oscillator, Morse potential, Modified Poschl-Teller potential
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